Substitution Reactions of Haloarenes

IMPORTANT

Substitution Reactions of Haloarenes: Overview

This Topic covers sub-topics such as Nucleophilic Substitution Reactions of Haloarenes and Mechanism of Nucleophilic Substitution Reactions of Haloarenes

Important Questions on Substitution Reactions of Haloarenes

MEDIUM
IMPORTANT

The correct order of reactivity of following haloarenes towards nucleophilic substitution with aqueous NaOH is:

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Choose the correct answer from the options given below:

HARD
IMPORTANT

The cumulative effect of their fluorine activate the rings of penta and hexa fluorobenzene toward nucleophilic aromatic substitution. What is compound X in the following synthesis?

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MEDIUM
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Which of the following aryl chlorides on warming with water forms the corresponding phenol?

MEDIUM
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Which of the following is CORRECT statement with respect to nucleophile substitution?

MEDIUM
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In the following reaction, the nucleophile (MeO ) will displace which of the halogen atoms most readily?

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MEDIUM
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Arrange the following compounds in incrensing order of their rate of reaction towards hydroxyl ion OH-.

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IIQuestion Image

III Question Image

IV Question Image

MEDIUM
IMPORTANT

Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards _____  substitution.(nucleophilic/electrophilic)

EASY
IMPORTANT

The rates of reaction of NaOH with:

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follow the order:-

EASY
IMPORTANT

In the questions arrange the compounds in increasing order of rate of reaction towards nucleophilic substitution.

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MEDIUM
IMPORTANT

Which among the following statements is true about reactivity of haloarenes towards nucleophilic substitution reactions?
1. Haloarenes are very reactive towards nucleophilic substitution reaction.
2. In haloarenes, the C-X bond acquires partial double bond character.
3. The C-X bond in haloarenes is longer than the C-X bond in haloalkanes.
4. In haloarenes, the phenyl cation formed as a result of self-ionization is stable.

MEDIUM
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Given reaction will be faster, when X is:

MEDIUM
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Aromatic nucleophilic substitution (SNAr) with fastest rate is given by -

MEDIUM
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Select correct statement(s):

HARD
IMPORTANT

Which of the following is the most reactive towards nucleophilic aromatic substitution?

MEDIUM
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In the given reaction

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'A' can be

MEDIUM
IMPORTANT

In the reaction of p-chlorotoluene with NaNH2 in liquid NH3, the major product is:

EASY
IMPORTANT

What is the major organic product of the reaction?

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MEDIUM
IMPORTANT

Which of the aromatic compounds react fastest with methoxide ion?

EASY
IMPORTANT

Which of the following compounds will not react with ethanolic KCN?

EASY
IMPORTANT

The major product (P) in the following reaction
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